Cruise: 35MF20020104 (dataset:CARINA) Data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Synonyms (including errata!) for this cruise: OISO 8; 35MF20020104; OISO-8
IMPORTANT information for GLODAP Reference Group Editors: This adjustment is a published version for GLODAPv2!
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35MF20020104 - 2008-06-17 14:28:38 - version: 0Posted on 2008-06-17 14:28:38 - last updated on 2008-06-17 14:28:38 as version number 0
1/22/08 this file initialized
Data from C. LoMonaco 1/8/08
Cruise dates: 1/4-2/1/2002
Chief Scientist: N. Metzl
Ship and cruise designation:Marion-Dufresne; OISO-8
EXPOCODE: 35MF20020104
Region: OISO area SE of South Africa
13 stations; with 24 place Rosette
Hydro: Who - N.Metzl; Status - final; S Plus - up to date
Notes: both CTD and bottle salts
Nuts/O2: Who - N.Metzl; Status - final; S Plus - up to date
Notes: both ctd and bottle oxygen
TCO2: Who - C. Lo Monaco; Status - final; S Plus - up to date
Notes: CRM batch #52
TA: Who - C. Lo Monaco; Status - final; S Plus - up to date
Notes: CRM batch #52
fCO2: Who - ; Status - ; S Plus -
Notes:
pH25: Who - ; Status - not measured; S Plus -
Notes:
CFC: Who - ; Status - not measured; S Plus -
Notes:
C-14: Who - ; Status - not measured; S Plus -
Notes:
C-13: Who - ; Status - collected; S Plus -
Notes:
H-3/He-3: Who - ; Status - not measured; S Plus -
Notes:
Other: O18 - collected, file has ChlorophylA and Fluorescence (volts)
References:
View comment(s) (filtered by salinity in subject)
Autogenerated CTD salinity and CTD oxygen update
Automated update! This overwrites adjustment values (and flags) of CTDoxy and
CTDsal with the values from BOTsal and BOToxy for every cruise, unless CTDsal
(or CTDoxy) is not present or bad.
Salinity action ID:5; CTD salinity data good, setting CTD salinity offset and QC
flag to bottle values.
Oxygen action ID:5; CTD oxygen data good, setting CTD oxygen offset and QC flag
to bottle values.
Posted by svheuven@gmail.com on 2015-02-19 09:22:19 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/salinity: update slope+intercept
autogenerated: BOTsal is compatible with unchanged CTDsal
Posted by svheuven@gmail.com on 2014-12-18 16:52:45 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - salinity
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/salinity: init slope+intercept
autogenerated: using mean of BOTsal and UNCHANGED CTDsal
Posted by svheuven@gmail.com on 2014-02-25 17:02:15 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - salinity
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is -2.5 (+/-9.4)
ppm.
7 cross overs show no significant differences (<5 ppm) and involve cruises that
are thought to have no significant offset in salinity. When the offsets
suggested for the other cruises are taken into account the average of all cross
overs is +0.7 (+/-1.9) ppm. This suggests that no adjustment would be required.
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show offsets of
-1 (+/-7) ppm and -2(+/-2) ppm, respectively, which supports no adjustment.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for salinity.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:55:34 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by ctd_salinity in subject)
Autogenerated CTD salinity and CTD oxygen update
Automated update! This overwrites adjustment values (and flags) of CTDoxy and
CTDsal with the values from BOTsal and BOToxy for every cruise, unless CTDsal
(or CTDoxy) is not present or bad.
Salinity action ID:5; CTD salinity data good, setting CTD salinity offset and QC
flag to bottle values.
Oxygen action ID:5; CTD oxygen data good, setting CTD oxygen offset and QC flag
to bottle values.
Posted by svheuven@gmail.com on 2015-02-19 09:22:19 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by tco2 in subject)
Autogenerated comment - tCO2
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - tco2
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is -6.6 (+/-2.2)
umol/kg.
Only 2 cross overs show no significant differences (<4 umol/kg), one of them
involving a cruise that is thought to have no offest in TCO2 values. The 9
others show offsets ranging from -4.5 to -9.4 umol/kg, which suggests that the
cruise would have low TCO2 values. When the suggested offsets are taken into
account the average of all cross overs is -6.5 (+/-1.9) umol/kg. This suggests
that an adjustment of +6.5 umol/kg could be required.
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show offsets of
-15.7 (+/-2.7) umol/kg and -13.3 (+/-1.8) umol/kg, repectively. But since the
cruises INDIGO1 and INDIGO3 are known to have high TCO2 values by about 10
umol/kg and 6 umol/kg respectively (according to this study and GLODAP), the
differences translate into offsets of about -6 umol/kg and -7 umol/kg,
respectively. This supports the result of the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest an adjustment of +6.5 umol/kg for
TCO2.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:56:08 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by alkalinity in subject)
Autogenerated comment - alkalinity
Automated update setting data quality flag from BAD to GOOD in order to retain
these non-QCed data in final product. SvH/GLODAPv2 / 2015-01-19)
Posted by svheuven@gmail.com on 2015-01-20 14:46:42 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - alkalinity
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : set to -888
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - alkalinity
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
9 cross overs were analyzed. The average of all cross overs is -2.6 (+/-3.7)
umol/kg.
All cross overs but 2 show no significant differences (<5 umol/kg) and involve
cruises that are thought to have no offset in alkalinity. This suggests that no
adjustment would be required.
Note that cross overs found at 56°S show a large scatter around the mean (-2.5
+/-3.4 umol/kg), probably due to natural variability. And indeed, if a decrease
in alkalinity of 1 umol/kg/yr is assumed (as suggested in this study) the
scatter and the mean are reduced (-1.0 +/-1.6 umol/kg).
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show differences
of -17.9 (+/-1.4) umol/kg and -16.6 (+/-3.7) umol/kg, respectively, but INDIGO1
is known to have high alkalinity values by about 16 umol/kg and INDIGO3 would
have no offset but alkalinity might have decreased by about 15 umol/kg. If this
is taken into account the offsets with INDIGO cruises translate into no
significant differences, which supports the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for alkalinity.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:56:40 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by ph in subject)
Autogenerated comment - phosphate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by nitrate in subject)
Autogenerated comment - nitrate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : make 1.05.
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - nitrate
OISO8: only one deep profile for nitrate (at 56°S).
INTERNAL OISO CONSISTENCY:
6 cross overs were analyzed. The average of all cross overs is 0.933 (+/-0.047).
All cross overs show significant differences ranging from 0.85 to 0.98. Only one
of them involves a cruise that is thought to have no offset in nitrate and
appears reliable (0.955 +/-0.005 with 35MF20010103). When the natural changes in
nitrate suggested for the other cruises are taken into account, the average of
all cross overs is 0.961 (+/-0.004). This suggests that an adjustment of 1.04
could be required, but it is not warranted since Antarctic deep waters are
entitled to natural variability, which could play a role in the observed
differences (all cross overs are found at 56°S).
OTHER CROSS OVERS:
The cross over with the cruise INDIGO3 shows a ratio of 0.997 (+/-0.016), but
INDIGO3 is thought to have low nitrate values. When the suggested offset is
taken into account as well as the suggested natural variability, it translates
into an offset of 0.963. This supports the analysis above.
CONCLUSION:
Given the large uncertainty attached to the regional analyses above due to
natural variability in the Antarctic region, I have no recommendation for
nitrate.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:24:47 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by phosphate in subject)
Autogenerated comment - phosphate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by silicate in subject)
Autogenerated comment - silicate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain. I cannot solve
these 35MF cruises for Silicate, and by this stage will happily just accept
anything Clair suggested for them.
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - silicate
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is 0.952
(+/-0.039).
Only 2 cross overs found at 30°S show no significant differences (<2%) but they
involve cruises that are thought to have low silicate. When the suggested
offsets are taken into account the average of the 5 cross overs found at 30°S is
0.964 (+/-0.006). This suggests that an adjustment of 1.04 could be required.
At 56°S, however, 1 reliable cross over which involves a cruise that is thought
to have no offset in silicate suggests an offset of 1.070 (+/-0.008). When the
offsets suggested for the other cruises as well as the suggested natural
variability are taken into account the average of the 6 cross overs is 0.938
(+/-0.002). This suggests that a large adjustment would be required, but it is
not warranted since Antarctic deep waters are entitled to natural variability
which could mask the offset observed at 30°S.
OTHER CROSS OVERS:
The cross over with the cruise INDIGO1 (30°S) shows a ratio of 0.979 (+/-0.009),
in good agreement with the analysis above (INDIGO1 is thought to have slightly
low silicate).
The cross over with the cruise INDIGO3 (56°S) shows a ratio of 0.877 (+/-0.009),
but INDIGO3 is thought to have high silicate values. When the suggested offset
is taken into account as well as the suggested natural variability, a good
agreement is found with the OISO analysis above (0.943).
CONCLUSION:
The different results obtained at 30°S and 56°S are probably due to natural
changes that would have operated in Antarctic deep waters as suggested by the
analysis of other parameters including salinity.
Based on this I suggest an adjustment of 1.04 for silicate.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:25:14 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by oxygen in subject)
Autogenerated CTD salinity and CTD oxygen update
Automated update! This overwrites adjustment values (and flags) of CTDoxy and
CTDsal with the values from BOTsal and BOToxy for every cruise, unless CTDsal
(or CTDoxy) is not present or bad.
Salinity action ID:5; CTD salinity data good, setting CTD salinity offset and QC
flag to bottle values.
Oxygen action ID:5; CTD oxygen data good, setting CTD oxygen offset and QC flag
to bottle values.
Posted by svheuven@gmail.com on 2015-02-19 09:22:19 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/oxygen: update slope+intercept
autogenerated: BOToxy is compatible with unchanged CTDoxy
Posted by svheuven@gmail.com on 2014-12-18 16:52:45 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - oxygen
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/oxygen: init slope+intercept
autogenerated: using BOToxy because bad fit of CTDoxy.
Posted by svheuven@gmail.com on 2014-02-25 17:02:15 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - oxygen
OISO8: only one deep profiles (at 56°S).
INTERNAL OISO CONSISTENCY:
6 cross overs were analyzed. The average of all cross overs is 1.013 (+/-0.028).
3 cross overs show no significant differences (<1%) and involve cruises that are
thought to have no offset in oxygen. When the offsets suggested for the other
cruises are taken into account the average of all cross overs is 1.002
(+/-0.003). This suggests that no adjustment would be required.
OTHER CROSS OVERS:
The cross over with the cruise INDIGO3 shows a ratio of 1.010 (+/-0.005), in
relatively good agreement with the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for oxygen.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:25:31 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View comment(s) (filtered by ctd_oxygen in subject)
Autogenerated CTD salinity and CTD oxygen update
Automated update! This overwrites adjustment values (and flags) of CTDoxy and
CTDsal with the values from BOTsal and BOToxy for every cruise, unless CTDsal
(or CTDoxy) is not present or bad.
Salinity action ID:5; CTD salinity data good, setting CTD salinity offset and QC
flag to bottle values.
Oxygen action ID:5; CTD oxygen data good, setting CTD oxygen offset and QC flag
to bottle values.
Posted by svheuven@gmail.com on 2015-02-19 09:22:19 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
View 19 comment(s) (Lists all comments)
Autogenerated CTD salinity and CTD oxygen update
Automated update! This overwrites adjustment values (and flags) of CTDoxy and
CTDsal with the values from BOTsal and BOToxy for every cruise, unless CTDsal
(or CTDoxy) is not present or bad.
Salinity action ID:5; CTD salinity data good, setting CTD salinity offset and QC
flag to bottle values.
Oxygen action ID:5; CTD oxygen data good, setting CTD oxygen offset and QC flag
to bottle values.
Posted by svheuven@gmail.com on 2015-02-19 09:22:19 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - alkalinity
Automated update setting data quality flag from BAD to GOOD in order to retain
these non-QCed data in final product. SvH/GLODAPv2 / 2015-01-19)
Posted by svheuven@gmail.com on 2015-01-20 14:46:42 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/oxygen: update slope+intercept
autogenerated: BOToxy is compatible with unchanged CTDoxy
Posted by svheuven@gmail.com on 2014-12-18 16:52:45 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/salinity: update slope+intercept
autogenerated: BOTsal is compatible with unchanged CTDsal
Posted by svheuven@gmail.com on 2014-12-18 16:52:45 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - oxygen
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - silicate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain. I cannot solve
these 35MF cruises for Silicate, and by this stage will happily just accept
anything Clair suggested for them.
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - phosphate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - nitrate
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : make 1.05.
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - alkalinity
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : set to -888
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - tCO2
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
Autogenerated comment - salinity
Auto-uploaded comment from GLODAPv2 assessment by Steven van Heuven (src:
GLODAPv2 Adjustment IND and PAC_SvH_20140611.xlsx): : maintain
Posted by svheuven@gmail.com on 2014-06-16 15:50:37 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/oxygen: init slope+intercept
autogenerated: using BOToxy because bad fit of CTDoxy.
Posted by svheuven@gmail.com on 2014-02-25 17:02:15 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104/salinity: init slope+intercept
autogenerated: using mean of BOTsal and UNCHANGED CTDsal
Posted by svheuven@gmail.com on 2014-02-25 17:02:15 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - oxygen
OISO8: only one deep profiles (at 56°S).
INTERNAL OISO CONSISTENCY:
6 cross overs were analyzed. The average of all cross overs is 1.013 (+/-0.028).
3 cross overs show no significant differences (<1%) and involve cruises that are
thought to have no offset in oxygen. When the offsets suggested for the other
cruises are taken into account the average of all cross overs is 1.002
(+/-0.003). This suggests that no adjustment would be required.
OTHER CROSS OVERS:
The cross over with the cruise INDIGO3 shows a ratio of 1.010 (+/-0.005), in
relatively good agreement with the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for oxygen.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:25:31 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - silicate
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is 0.952
(+/-0.039).
Only 2 cross overs found at 30°S show no significant differences (<2%) but they
involve cruises that are thought to have low silicate. When the suggested
offsets are taken into account the average of the 5 cross overs found at 30°S is
0.964 (+/-0.006). This suggests that an adjustment of 1.04 could be required.
At 56°S, however, 1 reliable cross over which involves a cruise that is thought
to have no offset in silicate suggests an offset of 1.070 (+/-0.008). When the
offsets suggested for the other cruises as well as the suggested natural
variability are taken into account the average of the 6 cross overs is 0.938
(+/-0.002). This suggests that a large adjustment would be required, but it is
not warranted since Antarctic deep waters are entitled to natural variability
which could mask the offset observed at 30°S.
OTHER CROSS OVERS:
The cross over with the cruise INDIGO1 (30°S) shows a ratio of 0.979 (+/-0.009),
in good agreement with the analysis above (INDIGO1 is thought to have slightly
low silicate).
The cross over with the cruise INDIGO3 (56°S) shows a ratio of 0.877 (+/-0.009),
but INDIGO3 is thought to have high silicate values. When the suggested offset
is taken into account as well as the suggested natural variability, a good
agreement is found with the OISO analysis above (0.943).
CONCLUSION:
The different results obtained at 30°S and 56°S are probably due to natural
changes that would have operated in Antarctic deep waters as suggested by the
analysis of other parameters including salinity.
Based on this I suggest an adjustment of 1.04 for silicate.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:25:14 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - nitrate
OISO8: only one deep profile for nitrate (at 56°S).
INTERNAL OISO CONSISTENCY:
6 cross overs were analyzed. The average of all cross overs is 0.933 (+/-0.047).
All cross overs show significant differences ranging from 0.85 to 0.98. Only one
of them involves a cruise that is thought to have no offset in nitrate and
appears reliable (0.955 +/-0.005 with 35MF20010103). When the natural changes in
nitrate suggested for the other cruises are taken into account, the average of
all cross overs is 0.961 (+/-0.004). This suggests that an adjustment of 1.04
could be required, but it is not warranted since Antarctic deep waters are
entitled to natural variability, which could play a role in the observed
differences (all cross overs are found at 56°S).
OTHER CROSS OVERS:
The cross over with the cruise INDIGO3 shows a ratio of 0.997 (+/-0.016), but
INDIGO3 is thought to have low nitrate values. When the suggested offset is
taken into account as well as the suggested natural variability, it translates
into an offset of 0.963. This supports the analysis above.
CONCLUSION:
Given the large uncertainty attached to the regional analyses above due to
natural variability in the Antarctic region, I have no recommendation for
nitrate.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-21 14:24:47 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - alkalinity
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
9 cross overs were analyzed. The average of all cross overs is -2.6 (+/-3.7)
umol/kg.
All cross overs but 2 show no significant differences (<5 umol/kg) and involve
cruises that are thought to have no offset in alkalinity. This suggests that no
adjustment would be required.
Note that cross overs found at 56°S show a large scatter around the mean (-2.5
+/-3.4 umol/kg), probably due to natural variability. And indeed, if a decrease
in alkalinity of 1 umol/kg/yr is assumed (as suggested in this study) the
scatter and the mean are reduced (-1.0 +/-1.6 umol/kg).
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show differences
of -17.9 (+/-1.4) umol/kg and -16.6 (+/-3.7) umol/kg, respectively, but INDIGO1
is known to have high alkalinity values by about 16 umol/kg and INDIGO3 would
have no offset but alkalinity might have decreased by about 15 umol/kg. If this
is taken into account the offsets with INDIGO cruises translate into no
significant differences, which supports the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for alkalinity.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:56:40 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - tco2
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is -6.6 (+/-2.2)
umol/kg.
Only 2 cross overs show no significant differences (<4 umol/kg), one of them
involving a cruise that is thought to have no offest in TCO2 values. The 9
others show offsets ranging from -4.5 to -9.4 umol/kg, which suggests that the
cruise would have low TCO2 values. When the suggested offsets are taken into
account the average of all cross overs is -6.5 (+/-1.9) umol/kg. This suggests
that an adjustment of +6.5 umol/kg could be required.
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show offsets of
-15.7 (+/-2.7) umol/kg and -13.3 (+/-1.8) umol/kg, repectively. But since the
cruises INDIGO1 and INDIGO3 are known to have high TCO2 values by about 10
umol/kg and 6 umol/kg respectively (according to this study and GLODAP), the
differences translate into offsets of about -6 umol/kg and -7 umol/kg,
respectively. This supports the result of the analysis above.
CONCLUSION:
Based on the regional analyses above I suggest an adjustment of +6.5 umol/kg for
TCO2.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:56:08 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
35MF20020104 - salinity
OISO8: two deep profiles (at 30°S and 56°S).
Note: these 2 stations are treated as different cross overs in the analysis
below.
INTERNAL OISO CONSISTENCY:
11 cross overs were analyzed. The average of all cross overs is -2.5 (+/-9.4)
ppm.
7 cross overs show no significant differences (<5 ppm) and involve cruises that
are thought to have no significant offset in salinity. When the offsets
suggested for the other cruises are taken into account the average of all cross
overs is +0.7 (+/-1.9) ppm. This suggests that no adjustment would be required.
OTHER CROSS OVERS:
The cross overs with cruises INDIGO1 (30°S) and INDIGO3 (56°S) show offsets of
-1 (+/-7) ppm and -2(+/-2) ppm, respectively, which supports no adjustment.
CONCLUSION:
Based on the regional analyses above I suggest no adjustment for salinity.
___________________
Paris, August 2008
Claire Lo Monaco
Posted by claire.lomonaco@locean.upmc.fr on 2008-10-08 23:55:34 UTC for data product: CARINA, GLODAPv2, v2.2019, v2.2020, v2.2021, v2.2022, v2.2023
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